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A synthesis of some derivatives of alkaloids. VIII

L. Dúbravková, I. Ježo, P. Šefčovič, and Z. Votický

Slovak Academy of Sciences, Bratislava

 

Abstract: cf. C.A. 50, 373g. Two model substances of emetine were prepd. by synthesis: 2-(3,4-dimethoxyphenyl)-4-methylpiperidine HCl salt, from veratrole by way of 3,4-(MeO)2C6H3COCH2CHMeCH2CO2Me and 2-(3,4-dimethoxyphenyl)-4-methyl-6-oxopiperidine, and 2-methyl-4-oxo-8,9-(3,4-dimethoxybenzo)quinolizidine HCl salt, from homoveratrylamine by way of 3,4-(MeO)2C6H3CH2NHCOCH2CHMeCH2CO2Me and 1-(2-methyl-3-carbomethoxypropyl)-3,4-dihydro-6,7-dimethoxyisoquinoline.

Full paper in Portable Document Format: 103a156.pdf (in Slovak)

 

Chemical Papers 10 (3) 156–161 (1956)

Monday, April 19, 2021

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