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Study of l-phenylacetylcarbinol. V

Š. Bauer, L. Masler, Š. Országh, J. Mokrý, and J. Tomko

Slovak Academy of Sciences, Bratislava

 

Abstract: cf. C.A. 51, 8037e. Metals of group VIII (Fe, Co, Ni) (I) in amts. of about 0.1% racemize l-phenylacetylcarbinol (II). It was impossible to purify tech. pure II by distn. under low pressure if II was prepd. in app. contg. I. The addn. of ethylenediaminetetraacetic acid in the amts. equal to I present in II inhibited the racemization even at higher temps. so that distn. is possible.

Full paper in Portable Document Format: 1111a651.pdf (in Slovak)

 

Chemical Papers 11 (11) 651–655 (1957)

Monday, July 15, 2019

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