ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Catalysts for vinyl chloride. IV. Reaction intermediates formed during synthesis in the presence of water

J. Janda

Research Institute for Acetylenchemistry, Nováky

 

Abstract: cf. C.A. 52, 8933c. The prepn. and properties of some unknown compds. formed during the synthesis of CH2:CHCl (I) on HgCl2 catalysts in the presence of H2O are described. The formula for the final compd. was found to be OHCC(HgCl)2HgOHgC(HgCl)2CHCl2. Contrary to former opinions, HgCl2 catalyzes the formation of I even if not spread on matter having a large specific surface.

Full paper in Portable Document Format: 121a37.pdf (in Slovak)

 

Chemical Papers 12 (1) 37–47 (1958)

Saturday, October 12, 2024

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