ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Synthesis of some derivatives of alkaloids. XVI

K. Babor, I. Ježo, V. Kaláč, and M. Karvaš

Slovak Academy of Sciences, Bratislava

 

Abstract: cf. C.A. 53, 17162e. (±)-1-(Hydroxymethyl)pyrrolizidine (picrate m. 190-3°, n24D 1.4987) was synthesized from γ-chlorobutyraldehyde, of its di-Et acetal, and from γ-aminobutyraldehyde di-Et acetal through γ,γbis(diethoxymethyl)di-n-propylamine (I), b2.5 158-61°, n25D 1.4378, and 1-formylpyrrolizidine. It was detd. that the intramol. condensation occurred only at pH 4.2; at pH below 4 polymers formed and at pH above 5 some of the original substance did not react.

Full paper in Portable Document Format: 133a163.pdf (in Slovak)

 

Chemical Papers 13 (3) 163–169 (1959)

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