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Kinetics of AgO decomposition

B. Stehlík

J. Ev. Purkyně University, Brno

 

Abstract: Ag2O3 decomp. into Ag2O in the dry state very rapidly and irregularly in the beginning and later with a 1st-order reaction rate, with an activation energy of 22 kcal./mol. In H2O and 1N KOH it decomp. into AgO with 1st-order reaction rate and with the same activation energy. The formation of AgO can be explained by the dismutation equil. between ions of bi-, tri-, and univalent Ag.

Full paper in Portable Document Format: 157a474.pdf (in Czech)

 

Chemical Papers 15 (7) 474–478 (1961)

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