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Laboratory preparation of trimethylvinylsilane

I. Šimek and J. Alač

Slovak Technical University, Bratislava

 

Abstract: The effect of some reaction conditions on the yield of Wurtz synthesis of trimethylvinylsilane (I) by Na condensation (Kanazashi, CA 49, 11578e) is described. By applying statistical data of latin squares and graphical data, optimum reaction conditions based on 1 mole I are given: equimolar ratio of Me3SiCl to CH2:CHCl to Na, 200 cc. ether, the speed of flow of vinyl chloride 16-20 g./hr. Yield was increased up to 80.0% and 82.1% compared with 77.5 reported by Kanazashi.

Full paper in Portable Document Format: 154a278.pdf (in Slovak)

 

Chemical Papers 15 (4) 278–282 (1961)

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