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Application of oscillographic polarography or reaction kinetic measurements. II

G. Dušinský

Staatliches Institut für Heilmittelkontrolle, Bratislava

 

Abstract: cf. CA 55, 15182i. By oscillographic polarography, the rate of alk. hydrolysis of esters of p-aminobenzoic acid: benzocaine (I), procaine (II), and Larocaine (III); Et nicotinate (IV), isonicotinate (V), and picolinate (VI); Ph salicylate (VII), arecoline (VIII); and penicillin G (IX), decompd. in alk. medium, was measured. The activation energy was detd. as I 11.6, II 11.4, III 7.43, IV 14.3, V 12.5, VI 13.7, VII 19.6, VIII 11.5, and IX 10.1 kcal./mole.

Full paper in Portable Document Format: 174a265.pdf (in Slovak)

 

Chemical Papers 17 (4) 265–267 (1963)

Monday, June 21, 2021

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