ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Adonitoxol, a new cardiac glycoside of Adonis vernalis

A. Cserép, L. Masler, D. Šikl, and Š. Bauer

Institute of Chemistry, Department of Biochemistry of Saccharides, Slovak Academy of Sciences, Bratislava

 

Abstract:  Two crystalline cardiac glycosides, adonitoxin and adonitoxol have been isolated from the ethanol extracts of the dry plants of Pheasant's eye (Adonis vernalis L.) through counter-current distribution in the system toluene—butanol—water 2 1:3 and chromatography over alumina. Adonitoxol (C29H44O10) was determined to be L-rhamnosideadonitoxologenin. The structure of adonitoxol isolated from the natural material was proved by comparing analysis with adonitoxol prepared from adonitoxin by sodium borohydride reduction.

Full paper in Portable Document Format: 184a273.pdf (in Slovak)

 

Chemical Papers 18 (4) 273–280 (1964)

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