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The solubility of gases in nonelectrolyte mixtures. The solubility of carbon dioxide in the binary nonaqueous mixtures

L. Koudelka

Forschungsinstitut für Petrolchemie, Nováky

 

Abstract: The soly. of CO2 at 20° and at the partial pressure of the gas at 760 torr was measured in MeOH-acetone, MeOH-CHCl3, MeOH-C6H6, acetone-CHCl3, acetone-C6H6 and CHCl3-C6H6. For the measurements an app. was constructed. The soly. of the gas does not change linearly with the concn. of the components. For a better evaluation, Krichevskii's (CA 31, 41868) equation and an activity coeff. equation were applied. Good results were obtained in MeOH-acetone and CHCl3-C6H6, but in the others the exptl. error was up to 20%.

Full paper in Portable Document Format: 183a178.pdf (in Slovak)

 

Chemical Papers 18 (3) 178–185 (1964)

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