ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Calcium sulphate scaling in membrane distillation process
Department of Water Technology and Environment Engineering, Institute of Chemical and Environment Engineering, Szczecin University of Technology, ul. Puŀaskiego 10, 70-322 Szczecin, Poland
Received: 30 March 2008 Revised: 3 July 2008 Accepted: 21 July 2008
Abstract: Formation of precipitates containing CaSO4 during membrane distillation, applied to the concentration of aqueous salt solutions, is discussed in this paper. It was
found that the concentration of SO42− ions in such solutions should not exceed 600 mg L−1 when they are subjected to concentration. However, concentration of sulphates at the level of 800 mg L−1 in the feed is permissible provided that the excess of CaSO4 is removed in a crystallizer. Crystallisation of salts, mainly CaSO4 · 2H2O, on the surface and inside the membrane was observed at higher feed concentrations, causing damage of the module. Precipitation
of calcium sulphate was also observed during the production of demineralised water when high values of the water recovery
coefficient (above 90 %) were used. In this case, the formed precipitate also contained CaCO3, the co-precipitation of which significantly changed the properties of the scaling layer. The precipitate containing both
CaSO4 and CaCO3 was formed mainly on the membrane surface and it could easily be removed by rinsing the module with a HCl solution.
Keywords: membrane distillation - scaling - calcium sulphate - water pretreatment
Full paper is available at www.springerlink.com.
Chemical Papers 63 (2) 146–151 (2009)
Wednesday, February 26, 2020