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Aminolysis of sucrose. VII. Reaction between sucrose and an aqueous solution of dimethylamine at higher temperatures

I. Ježo and I. Lužák

Slovak Academy of Sciences, Bratislava 9

 

Abstract: cf. preceding abstr. From the mixt., formed by the reaction of sucrose with an aq. soln. of Me2NH at higher temps., the following compds. were isolated and identified: Me3N, Me2NEt, 2-dimethylaminoethanol, 1,2-bis(dimethylamino)propane, 1,1,2-tris(dimethylamino)ethane, AcNMe2 N,N-dimethylglycolamide, N,N,N',N'-tetramethylglycinamide, and bis(dimethylamide) of cis(?)-tetrahydrofuran-2,5-dicarboxylic acid. A reaction mechanism is given.

Full paper in Portable Document Format: 1912a908.pdf (in Slovak)

 

Chemical Papers 19 (12) 908–917 (1965)

Thursday, November 14, 2019

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