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Effect of pressure and temperature on the isomerization of Cu(NH3)2Br2

J. Garaj and J. Gažo

Slovak Technical University, Bratislava

 

Abstract: The mutual change of α and β modifications of Cu(NH3)2Br2 (I) by isomerization at increased pressure and temp. was studied by x-ray methods. By increasing the pressure to 120-180 atm., α-I changes to β-I but there is never a complete change to pure β-I. The temp. has no effect on α-I. β-I changes rapidly to α-I if the temp. is increased to 84° and the time is shortened to 30 hrs.

Full paper in Portable Document Format: 206a458.pdf (in Slovak)

 

Chemical Papers 20 (6) 458–461 (1966)

Sunday, February 28, 2021

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