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Carbon dioxide production in the oscillating Belousov—Zhabotinsky reaction with oxalic acid

P. Ševčík, D. Mišicák, and Ľ. Adamčíková

Department of Physical and Theoretical Chemistry, Facully of Natural Sciences, Comenius University, SK-842 15 Bratislava, Slovakia

 

E-mail: sevcik@fns.uniba.sk

Received: 20 June 2005  Revised: 14 September 2005  Accepted: 20 September 2005

Abstract: A new volumetric method for monitoring the oscillating Belousov—Zhabotinsky reaction with oxalic acid is described. While an oscillatory behavior in the potential of the Pt redox electrode at slow stirring without inert gas bubbling can be observed, a monotonous, nonoscillatory course was found both at the slow and rapid stirring rates for the carbon dioxide evolution. Possible reasons for such observations are discussed.

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-006-0001-4

 

Chemical Papers 60 (1) 1–4 (2006)

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