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Polarography of 4-Substituted 4'-Isothiocyanatodiphenyl Sulfides

A. Beňo, M. Uher, and A. M. Kardoš

Department of Analytical Chemistry, Faculty of Natural Sciences, Komenský University, Bratislava 1

 

Abstract:  The Polarographie reduction of seven 4-substituted 4'-isothiocyanatodiphenyl sulfides was investigated in Britton —Robinson buffer solutions. The characteristic Polarographie data were either measured or calculated and the Qn,n reaction constant, obtained from the correlation of half-wave potentials with Hammett a constants was found to be 0.03 V.

Full paper in Portable Document Format: 234a275.pdf

 

Chemical Papers 23 (4) 275–280 (1969)

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