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Spectroscopic Investigations on Derivatives of Tetrahydrofuran. II. The Basicity of 2-Substituted Tetrahydrofurans

M. Kratochvíl, M. Sedláčková, A. Zahradníčková, and Z. Babák

Department of Organic Chemistry, J. E. Purkync University, Brno

 

Abstract: IR spectra of some complexes of 2-substituted tetrahydrofurans with phenol in carbon tetrachloride have been measured. v(OH) and Kas values can be correlated with Taft's σ* constants. The basicity of 2-substituted tetrahydrofurans under investigation increases proportionally with I-effects of the substituents. No steric effects have been found

Full paper in Portable Document Format: 252a137.pdf

 

Chemical Papers 25 (2) 137–141 (1971)

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