ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Preparation, isolation, and identification of 1,2,2-trichlorobutane
J. Vojtko, V. Rattay, and M. Hrušovský
Slovak Tech. Univ., Bratislava
Abstract: Chlorination of 1,2-dichlorobutane by elemental chlorine at 110°C in the
presence of SbCl5 as a catalyst resulted in a mixture of trichlorobutanes.
These were identified as 1,1,2-trichlorobutane, 1,2,3-trichlorobutane, and
1,2.4-trichlorobutane. Besides these compounds the reaction mixture contained
so far not described 1,2,2-trichlorobutane. The structure of the new
product was determined by spectral methods.
Full paper in Portable Document Format: 274a482.pdf (in German)
Chemical Papers 27 (4) 482–487 (1973)