ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Oxidation of benzyl alcohol by cobalt(III) acetylacetonate

J. Kotas, K. Veselý, and J. Pác

Research Institute of Macromolecular Chemistry, 656 49 Brno

 

Abstract:  The kinetics of cobalt (III) acetylacetonate oxidation of benzyl alcohol within 120— 140°C was followed by measuring the decrease of oxidation agent concentration spectrophotometrically. The formation of a complex consisting of one molecule of oxidation agent and one or two benzyl alcohol molecules preceded the oxidation reaction. The equilibrium constants of complex formation as well as the rate constants of complex oxidation conversion were determined. To complete the kinetic description of the process the equilibrium constants for alcohol association had to be determined.

Full paper in Portable Document Format: 285a638.pdf

 

Chemical Papers 28 (5) 638–645 (1974)

Thursday, March 28, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers