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Optical rotatory dispersion studies. IX. 2,3-Unsaturated esters of aldonic acids

T. Sticzay, C. Peciar, S. Bystrický, and S. Kučár

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract: Uv, ORD, and CD spectra of six 2,3-unsatd. aldonic acids were studied. The signs of Cotton effects in the 250 and 210 nm regions were related to the configuration of adjacent chiral centers. Aldonic acids with (4R)-configuration showed pos. Cotton effects in the 210 nm region and neg. Cotton effects in the 250 nm region; those with the (4S)-configuration showed opposite signs.

Full paper in Portable Document Format: 282a226.pdf

 

Chemical Papers 28 (2) 226–229 (1974)

Wednesday, November 13, 2019

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