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Thermodynamic analysis of the two-component systems LiF—NaF and NaF—NaCI

M. Malinovský and J. Gabčová

Department of Inorganic Technology, Slovak Technical University, 880 37 Bratislava


Abstract: The phase diagrams of the systems LiF-NaF and NaF-NaCl were studied using the classical thermal anal. method. The system LiF-NaF is a eutectic system with limited solid solns. of LiF in NaF, the extent of which is ∼8 mol% LiF. The coordinates of the eutectic point are LiF 60.5, NaF 39.5 mol%, tE = 652°. The system NaF-NaCl is a simple eutectic system with the eutectic point at NaF 66 mol%, NaCl 34 mol%, tE = 688.5°. The thermodn. anal. of the systems LiF-NaF and NaF-NaCl was performed on the basis of the exptl. results.

Full paper in Portable Document Format: 306a783.pdf


Chemical Papers 30 (6) 783–795 (1976)

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