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Reactions of saccharides catalyzed by molybdate ions. XVIII. Preparation of D-threo-L-talooctose and D-erythro-L-talooctose and their epimers

V. Bílik, L. Petruš, and J. Alföldi

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract: Nitromethane synthesis with the corresponding aldoheptoses followed by oxidative decomposition of the formed sodium salts of 1-deoxy-l-nitrooctitols led to preparation of D-erytro-L-galactooctose, D-erytro-L-talooctose, D-threo-L-galactooctose, and D-threo-L-talooctose. High efficiency of the separation on a Dowex 50 W ion exchanger (in the Ba2+ form) of the epimeric pairs of aldoses belonging to the homomorphous series of arabinose and ribose was demonstrated in nine cases.

Full paper in Portable Document Format: 305a698.pdf

 

Chemical Papers 30 (5) 698–702 (1976)

Wednesday, June 23, 2021

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