ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Kinetics of the redox reaction of the uranium(III) ions with hydrazoic acid

Ľ. Adamčíková and Ľ. Treindl

Department of Physical Chemistry, Faculty of Natural Sciences, Komenský University, S16 50Bratislava

 

Abstract: The kinetics and mechanism of the redox reaction of the U(111) ions with hydrazoic acid was studied. The rate equation is -d|U(III)|/dt = k|U(III)||HN3|. The activation parameters in the 0.4 M HCl are: ΔH* = 43.1 KJ mol-1 and ΔS* = -142.3 J mol-1 K-1. The probable reaction mechanism and the influence of the nature of the solvent in binary solvent mixts. (water-methanol, water-ethanol, water-isopropyl alc.) are discussed.

Full paper in Portable Document Format: 305a593.pdf

 

Chemical Papers 30 (5) 593–598 (1976)

Thursday, October 21, 2021

IMPACT FACTOR 2020
2.097
SCImago Journal Rank 2020
0.344
SEARCH
Advanced
VOLUMES
XXVIII. International Conference on Coordination and Bioinorganic Chemistry
© 2021 Chemical Papers