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Claisen rearrangement of allyl aryl ethers

J. Střešinka

Research Institute for Petrochemistry, 972 71 Nováky

 

Abstract:  The Claisen rearrangement of allyl aryl ethers was studied. On the basis of original results as well as the revaluation of the published results concerning the ortho- and para -Claisen rearrangement it has been proved that the ortho- and para -Claisen rearrangement is a reaction of the zero order. Only in a special case, provided the solvent is present in a great excess, the ortho- and para-Claisen rearrangement obeys the temporal law of the first-order reactions.

Full paper in Portable Document Format: 302a237.pdf

 

Chemical Papers 30 (2) 237–245 (1976)

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