ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Reaction of distortion isomers of dithiocyanatobis(pyridine)copper(II) with pyridine

M. Kabešová, B. Papanková, and J. Gažo

Department of Inorganic Chemistry, Slovak Technical University, 880 37 Bratislava


Abstract: Reactions of α- and ß-Cu(py)2(NCS)2 with pyridine are described. The conditions are specified under which a pair of modifications of Cu(py)4(NCS)2 complex is prepared by reactions of α- and ß-Cu(py)2(NCS)2 with pyridine as well as the conditions under which these reactions give rise to products with composition Cu(py)4(NCS)2 having the same physicochemical properties. The properties of prepared compounds were studied by thermal methods. Some properties of intermediate products of thermal decomposition of α- and ß-Cu(py)4(NCS)2 are also described. The differences between properties of prepared modifications suggest the presence of fine structural differences analogous to those observed for α- and ß-Cu(py)2(NCS)2.

Full paper in Portable Document Format: 301a35.pdf


Chemical Papers 30 (1) 35–41 (1976)

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