ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Calculation of thermodynamic excess functions in binary systems on the basis of isobaric phase equilibria and calorimetric measurements of changes in enthalpy

I. Proks

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

Abstract:  The general procedure of calculation of mixing parameters ∆S^E_mix and ∆G^E_mix in binary systems the components of which do not form compounds is presented. The excess functions can be calculated in this way assuming that the phase diagram of the system in question is known and that the corresponding enthalpies of mixing and of phase transitions are known in the chosen temperature range as well.

Full paper in Portable Document Format: 324a433.pdf

Chemical Papers 32 (4) 433–440 (1978)