ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Paramagnetic species in the reactions of organometallic reagents. VI. High-resolution ESR spectra of anion radicals
A. Staško, A. Tkáč, Ľ. Malík, V. Adamčík, and M. Hronec
Institute of Chemical Physics, Department of Physical Chemistry, Slovak Technical University,
880 37 Bratislava
Abstract: High-resolved electron spin resonance spectra of anion radicals of substrates
as ketones, enolates of β-diketones, quinones, sulfones, sulfoxides, nitro and
cyano compounds, aromates and heteroaromates were obtained in a relatively
simple procedure employing organometallic compounds as reduction agents.
Experimental and simulated spectra are presented and some general aspects of
this new method in the generation of anion radicals are discussed.
Full paper in Portable Document Format: 323a294.pdf
Chemical Papers 32 (3) 294–301 (1978)