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Kinetics and mechanism of redox reactions of the uranium(III) ions with monobromoacetic and monoiodoacetic acid

Ľ. Adamčíková and Ľ. Treindl

Department of Physical Chemistry, Faculty of Natural Sciences, Komenský University, 816 50Bratislava

 

Abstract: The kinetics and mechanism of redox reactions of U(III) ions with monobromoacetic and monoiodoacetic acid were studied. A probable reaction mechanism is proposed and kinetic measurements obtained with all 3 monohalogen acetic acids are compared. The influence of the binary water-tert-Bu alc. mixt. on kinetic parameters of these reactions as well as the application of the Marcus relation to expressing the ratio of rate consts. of the outer-sphere reactions shows that the redn. of the halogen acetic acids by U(III) ions follows an outer-sphere mechanism.

Full paper in Portable Document Format: 342a145.pdf

 

Chemical Papers 34 (2) 145–152 (1980)

Friday, November 22, 2019

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