ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Investigation of 8-mercaptoquinoline (thiooxine) and its derivatives. 109. Inner complex compounds of 2-phenyl- and 4-phenyl-8-mercaptoquinolines

J. Asaks, G. Yansons, J. Dobrovodsk√Ĺ, M. Zikmund, and J. Bankovskis

Institute of Inorganic Chemistry, Academy of Sciences of the Latvian SSR. 226 934 Riga


Abstract:  The interaction of 2-phenyl- and 4-phenyl-8-mercaptoquinoline with Zn(II), Cd(II), Hg(II), Ga(III), In(III), T1(I), Tl(III), Pb(II), Sn(II), Sn(IV), As(III), Sb(III), Bi(III), Mo(VI), W(VI), Mn(II), Re(VII), Cr(III), Ni(II), Co(II), Fe(II), Fe(III), V(IV), Cu(I), Cu(II), Ag(I), Au(I, III), Pd(II), Pt(II), Rh(III), Ir(III), Ru(III), and Os(IV) compounds in the system water—chloroform has been studied. Absorption spectra have been studied, composition and solubility of inner complex compounds in chloroform, the dependence of extraction of complexes with chloroform on hydrogen ion concentration in aqueous phase and stability constant of complexes in the system chloroform—water have been determined.

Full paper in Portable Document Format: 361a73.pdf


Chemical Papers 36 (1) 73–89 (1982)

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