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Kinetic study of the oxidation of malonic acid by manganese(III) ions

Ľ. Treindl and M. Mrákavová

Department of Physical Chemistry, Faculty of Natural Sciences and Institute of Chemistry, Komenský University, 842 IS Bratislava

 

Abstract: The oxidn. of malonic acid by the Mn(III) in H2SO4 is an important constituent of the Belousov-Zhabotinskii oscillating system. It is an inner-sphere redox reaction the first step of which is the formation of an intermediate complex. It is followed by the slow and rate-detg. formation of •CH(CO2H)2 and Mn(II)(SO4)n in a reversible reaction. The influence of O2 on the activation parameters is described.

Full paper in Portable Document Format: 365a627.pdf

 

Chemical Papers 36 (5) 627–632 (1982)

Thursday, April 18, 2024

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