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Realization and properties of a silver diethyldithiocarbamate electrode

J. Labuda, J. Mocák, and M. Skatuloková

Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: Metal-complex electrode was studied of the aq. Ag(I) diethyldithiocarbamate-diethyldithiocarbamate anion type. Formal potential values were assessed and the slope of graphic dependence of potential on the logarithm of relative concn. was detd. for the Ag and Ag-diethyldithiocarbamate electrodes, resp., in DMSO, MeOH as well as in H2O (ionic strength of NaClO4 soln. being 0.1 mol dm-3). Ag(Et2dtc) complexing is obsd. Values of its stability const. in the stated media as well as the value of its soly. product in water are given.

Full paper in Portable Document Format: 381a59.pdf

 

Chemical Papers 38 (1) 59–66 (1984)

Tuesday, April 23, 2024

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