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Wave-numbers of c=o stretching vibrations of exo-7-oxabicyclo[2.2.1]heptane-2,3-dicarboximide derivatives

A. Perjéssy and E. Sidóová

Department of Organic Chemistry, Faculty of Natural Sciences, Komensky University, CS-842 15 Bratislava

 

Abstract:  The wavenumbers of symmetric and antisymmetric C=0 stretching vibrations were measured for 46 derivatives of exo-7-oxabicyclo[2.2.1]heptane-2,3-dicarboximide in dilute solutions of tetrachloromethane and trichloromethane. A statistically significant correlation has been found between the wavenumbers of symmetric and antisymmetric C= 0 stretching vibrations    in the series of 87 experimental points obtained for values measured in both solvents. The relation between the slope of c,s(C= 0) vs. i.;as(C= 0) dependence and the structure of investigated compounds is discussed and compared with those for other five-membered cyclic imides and 1,3-dicarbonyl compounds.

Full paper in Portable Document Format: 396a755.pdf

 

Chemical Papers 39 (6) 755–761 (1985)

Monday, February 06, 2023

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