ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Influence of temperature, vanadium concentration, and degree of solution acidification on composition of the solid products .9. Products of the reactions taking place in acidified solutions of rubidium and cesium meta-vanadate and study of the 51V-NMR spectra of of aqueous solutions of polyvanadates
Ľ. Žurková, V. Suchá, and J. Schraml
Department of Inorganic Chemistry, Faculty of Natural Sciences,
Komenský University, CS-842 15 Bratislava
Abstract: It has been revealed on the basis of the 51V NMR spectra of aqueous
solutions of NaVO3 in acid region that the degree of their acidification and
temperature influence chemical shifts, i.e. the composition of solutions.
The optimum conditions of preparation of MI2V6O16 and RbHV6O16 have
been determined for the systems MIVO3—HNO3—H2O (MI=Rb,Cs).
Full paper in Portable Document Format: 395a629.pdf
Chemical Papers 39 (5) 629–637 (1985)