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Influence of temperature, vanadium concentration, and degree of solution acidification on composition of the solid products. 10. Products of the reactions taking place in acidified solutions of manganese(II) metavanadate

Č. Gőczeová

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, CS-842 15 Bratislava

 

Abstract: The influence of temperature, vanadium concentration, degree of solution acidification, and reaction time on composition of the solid polyvanadates arising from the system Mn(V03)2—HNO3—H20 was studied. Besides some products of varying composition, a compound of the composition Mn(HV6016) 2 .14H20 was obtained from the system. It results from the study of thermal properties of this substance that the process of water liberation is of gradual character and the full dehydration is succeeded by a decomposition of original structure yielding V205 and Mn(V03) 2 .

Full paper in Portable Document Format: 405a577.pdf

 

Chemical Papers 40 (5) 577–584 (1986)

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