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Benzothiazole compounds . 25. Kinetic-study of the reaction of 2-alkoxycarbonylmethylthio-3-alkylbenzothiazolium salts with water

A. Gáplovský and V. Sutoris

Institute of Chemistryу Komenský University, CS-842 15 Bratislava

 

Abstract: The stability of 2-alkoxycarbonylmethylthio-3-alkylbenzothiazolium salts in aqueous medium has been studied. The rate of hydrolysis was significantly dependent on the substituent in the position 3 as well as on the alkoxy group and pH of the medium. In the reaction medium 3-alkyl-2-benzothiazolinone was proved by spectral methods and esters of thioglycolic acid by gas chromatography.

Full paper in Portable Document Format: 401a115.pdf

 

Chemical Papers 40 (1) 115–119 (1986)

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