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Cobaltocene intercalate of the layered compounds SnSxSe2-x

J. Votinský, L. Beneš, J. Kalousová, P. Lošťák, and J. Klikorka

Institute of Chemical Technology, CS-532 10 Pardubice

 

Abstract: The layered SnSx.Se2-x (0≤x≤2) compounds react with cobaltocene vapour forming polycrystalline layer-type complexes with the composition of SnSxSe2-x . 0.33Co(C5H5)2. Intercalates have been studied by X-ray dif­fraction analysis and infrared absorption spectroscopy. Cobaltocene forms molecular monolayers between adjacent slabs of the host crystal structure, thefivefoldsymmetry axes of cobaltocene molecules lying parallel to the layers. The intercalation process involves an electron donation to the host, the cobaltocene being present as cobalticenium cation.

Full paper in Portable Document Format: 422a133.pdf

 

Chemical Papers 42 (2) 133–137 (1988)

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