ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Electroreduction of triose oximes

M. Fedoroňko, M. Petrušová, and J. Alfőldi

Institute of Chemistry, Centre for Chemical Research, Slovak Academy of Sciences, CS-84238 Bratislava

 

Abstract: The reaction of DL-glyceraldehyde and l,3-dihydroxy-2-propanone with hydroxylamine and the Polarographie behaviour of oximes obtained were investigated in aqueous buffer solutions. As found, Polarographie waves of these oximes in formate and acetate buffer solutions are pH-dependent within pH = 2—6. Both oximes were electroreduced on a preparative scale in the above-mentioned pH range of the reaction medium at potentiostatic and pH-static conditions. Mechanisms of the appropriate chemical and electrochemical reactions were proposed both from the Polarographie and preparative electroreductions and reaction products.

Full paper in Portable Document Format: 432a335.pdf

 

Chemical Papers 43 (2) 335–341 (1989)

Wednesday, November 13, 2019

IMPACT FACTOR 2018
1.246
SCImago Journal Rank 2018
0.274
SEARCH
Advanced
VOLUMES
International Conference on Coordination and Bioinorganic Chemistry
46th International Conference of SSCHE
© 2019 Chemical Papers