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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Possibilities of using some correlation relations based on linear relationship of the gibbs energies for studying the oxidation of ligands of some cobalt(III) complexes
O. Vollárová and J. Benko
Department of Physical Chemistry, Faculty of Natural Sciences,
Comenius University, CS-842 15 Bratislava
Abstract: In order to appreciate the reaction mechanism in a series of oxidations
of the ligands bonded in Co(III) complexes by different oxidizing agents
such as IO4-, S2O8-, and H202 , the correlations based on the principle of
linear relationship of the Gibbs energies were used. The results obtained for
oxidation of the ions [CoCyS(en)2]+, [CoCySO(en)2]+, [Co(en)2SCH2COO]+,
[Co(NH3)5NCS]2+, and [Co(dmgH)2(NCS)2]- were completed by the results
concerning the oxidation of the [Co(en)2SOCH2COO]+ ion by periodate.
Full paper in Portable Document Format: 444a567.pdf
Chemical Papers 44 (4) 567–574 (1990)
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