ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Kinetics of electrode reactions on metallic electrodes in pure molten chlorides

A. Kisza and J. Ka┼║mierczak

Institute of Chemistry, University of Wroclaw, PL-50-383 Wroclaw

 

Abstract: Using the relaxation method developed previously for the determination of the cathodic pseudo-first-order rate constant kc* and the faradaic impedance method for the determination of the double-layer capacitance Cd, the standard rate constant and the activation parameters of the electrode reaction in the electrode systems SnCl2(1)/Sn(1) and PbCl2(1)/Pb(1) have been determined.

Full paper in Portable Document Format: 452a187.pdf

 

Chemical Papers 45 (2) 187–194 (1991)

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