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Electrochemical Investigation of the Heterogeneous Equilibria in the Molten System Fe—Mn—Si—O/CaO—MgO—MnO—FeO—Al203—Si02

Š. Langová, A. Mališ, and J. Leško

Department of Chemistry, University of Mining and Metallurgy, CS-708 33 Ostrava

 

Abstract: Partial pressure of oxygen and activity of manganese monooxide in the molten system Fe-Mn-Si-O (1)/CaO-MgO-MnO-FeO-Al2O3-SiO2 (1) at the temperature of 1600°C was investigated using electrochemical methods. The dependence of the activity of MnO on its content in the mixture and on the optical basicity of the melt was determined. Dependence of the distribution coefficient of manganese on the partial pressure of oxygen and the optical basicity of the ionic melt was obtained.

Full paper in Portable Document Format: 473a165.pdf

 

Chemical Papers 47 (3) 165–168 (1993)

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