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ISSN electronic edition: 1336-9075
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Bis( O-Alkyl Dithiocarbonate)-Bis(Dicarbonyl- η5-cyclopentadienyliron)Tin(IV) Complexes

B. H. Chen, H. W. Jing, Y. Sh. Fan, Ch. M. Liu, and Y. X. Ma

Department of Chemistry, Lanzhou University, Lanzhou 730000, China

 

Abstract: Seven new complexes, [η5-C5H5Fe(CO)2]2Sn(S2COR)2 (R = alkyl), have been synthesized and characterized by elemental analysis, IR and 1H  NMR spectra. It has been proved that these O-alkyl dithiocarbonates are monobasic bidentate ligands to the tin ion. The coordination number of the central tin ion is six and we suggest an octahedral structure for these complexes.

Full paper in Portable Document Format: 515a283.pdf

 

Chemical Papers 51 (5) 283–285 (1997)

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