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(E)-Cinnamoylferrocene 5-Benzylcarbodithioylhydrazone and its Chelates

Guo-Sheng Huang, Yong-Hong Liu, Bao-Hua Chen, and Yong-Xiang Ma

Department of Chemistry, Lanzhou University, Lanzhou 730000, China

 

Abstract: A new organometallic compound, (E)-cinnamoylferrocene S-benzylcarbodithioylhydrazone (HCfbc) and its chelates with some metal(II) acetates, M(Cfbc)2.nH2O (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+, and Hg2+; n = 0-1) were prepared aad characterized by elemental analysis, IR, 1H NMR, and molar conductance. It is shown that HCfbc appears to be a bidentate ligand with trans configuration and to coordinate the metal through the azomethine nitrogen and thioenolic sulfur atom.

Full paper in Portable Document Format: 531a65.pdf

 

Chemical Papers 53 (1) 65–68 (1999)

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