ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Synthesis of pure selenium tetrachloride and its hydrolysis to selenium oxychloride

Z. Vavřín and R. Resl

Masaryk University, Brno

 

Abstract: A lab. process is described showing that by direct reaction of dry elementary Cl and dry elementary Se, and excluding even traces of humidity, 99.9% pure SeCl4 can be obtained. SeCl4 subjected to slow hydrolysis by introducing an inert gas (nitrogen) satd. with water vapor at room temp. gives well-defined SeOCl2. By measuring cond. of HCl soln. which is released during hydrolysis the change of SeCl4 into SeOCl2 can be checked.

Full paper in Portable Document Format: 85a241.pdf (in Czech)

 

Chemical Papers 8 (5) 241–254 (1954)

Monday, July 15, 2019

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