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Photochemistry of heterocycles. 19. Preparation and photochemistry of isoxazolines fused with naphthalene ring

L. Štibrányi, Ľ. Fišera, and K. Hubová

Department of Organic Chemistry, Slovak Technical University, CS-81237 Bratislava

 

Abstract: 1,3-Dipolar cycloaddition of X-substituted benzonitrile oxides, where X stands for H, 4-CH3, 4-Cl, 4-Br, 4-F, 4-N02, and 3-Cl, with 1,4-dihydronaphthalene is described. Photolysis of the thus prepared 3-aryl-3a,4,11,11a-tetrahydronaphthaleno[2,3-d]isoxazoles was studied and quantum yields measured from the diminishing concentration of the starting material. Preparation of benzodiazocino[3,4-d]isoxazoles is described.

Full paper in Portable Document Format: 421a59.pdf

 

Chemical Papers 42 (1) 59–66 (1988)

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